Branched Vinyl Polymers

It is expected that these branched polymers will be used as polymer rheological modifiers 1 2 3 4.

Branched vinyl polymers.

Also discovered is a vinyl polymer resin comprised of from 0 1 to 50 weight percent of non linear polymers having at least 0 06 branches 1000 backbone carbons where branching is measured using a heat polymerized polystyrene having from 0 0 to 0 06 branches 1000 backbone carbons as a linear reference. Architectural thermal and rheological characterization of the derived branched products. An approach to branched vinyl polymers through radical polymerization in the presence of 3 mercaptohexyl methacrylate mhm as the chain transfer monomer is reported in this paper. Application of the strathclyde route to branched vinyl polymers in suspension polymerization.

Table 1 summarises the results obtained. Reported the preparation of branched vinyl polymer through self condensing vinyl polymerization of an inimer scvp. In the case of polymerization at styrene100 mhm5 0 aibn2 0 the molecular weight increased with conversion and reached a value of 7 3 105 g mol at 99 conversion. In addition the zimm branching factor g.

Furthermore radical polymerization in the presence of the peroxide monomer can be operated in a simple polymerization composition involving only the. Manufacturing of vinyl acetate veova vinyl ester polymers is easy due to the favorable reactivity characteristics of the veova monomer and vinyl acetate. Copolymerisations of mma and bda were carried out in toluene solution under vacuum at 80 c using a standard methodology. It was not until 1995 that fréchet et al.

The copolymerization of hydrophobic vinyl ester of branched neo carboxylic acids significantly improves the performance of vinyl and acrylic binders. Synthesis of branched vinyl polymer using a balance of crosslinker and radical transfer agent. Veova vinyl esters have unique highly branched aliphatic structures which contribute to the enhancement of key polymer performance properties. Veova vinyl esters are commonly used in vinyl acetate and acrylic polymers where they greatly improve hydrolytic stability adhesion water and uv resistance.

Macromolecules 2009 42 20 7745 7752. Branched polymers of styrene methyl methacrylate mma and vinyl acetate vac were prepared under solvent free conditions through radical polymerization in the presence of a peroxide monomer.